For each Voronoi vertex you have its coordinates (xV,yV) and you know which three sites meet there — call one of them A with coordinates (xA,yA). Because at a vertex the distances to those three sites are all the same, you only need to compute the distance to one of them. Then repeat for every vertex and pick the one whose distance is the greatest.
Step 1 – Compute the distance at one vertex
dV=√(xV−xA)2+(yV−yA)2
Here (xV,yV) is the vertex and (xA,yA) is any one of its three equidistant sites.
Step 2 – Do the same for the other vertices
If the next vertex has coordinates (xW,yW) and meets site B at (xB,yB), compute
dW=√(xW−xB)2+(yW−yB)2
and so on for every vertex.
Step 3 – Compare your distances
Look at all your computed distances dV,dW,⋯. The vertex whose distance is the largest is the one that is farthest from its nearest toxic site. That vertex is where you should place the dump.